vB has the largest quantity of addons, as such a large number of them are free (and many also likely abandoned and not receiving updates). It also has a fair amount of good skins, but the load times leave much to be desired, especially in their recent vB 5. Honestly, I would avoid vB because of that; if you want to run a solid forum with access to most of the addons that have been released over the years, you'll need to install vB 4 which is no longer receiving major updates (still receiving security fixes, and MAYBE bugfixes, not sure on their version lifecycle). Major version upgrades (like 4 -> 5) cost money, although there is no yearly fee to keep your license active (although there IS a fee if you want to keep phone/ticket support active, you only get 30 days of it free with a new license purchase).
xenForo has a lot of very solid addons, quite a few of which paid but of all the paid addons I've purchased so far, they've been incredibly quality products. I find xenForo to be much faster and I also like the default skin a lot more, as well as quite a few of the custom ones. As long as you have an active license (yearly renewal fee) you have access to all current and future versions of xenForo (even major version upgrades) as well as ticket support.
I voted Xenforo.
